What is the largest?
The EU if you count it as a country, otherwise the USA.
https://en.wikipedia.org/wiki/List_of_countries_by_GDP_%28no...
https://en.wikipedia.org/wiki/List_of_countries_by_GDP_%28PP...
It is however limited when comparing the size of national economies; GDP PPP is designed to compare the purchasing power of the citizens of one country against those of another country rather than the total size of national economies.
So it doesn't seem appropriate for comparing the size of national economies.But by selling a hamburger in the US, you can buy several hamburgers in China...?