By splitting the addition up into two discrete calls, the ordering is made much more explicit, there's no room for ambiguity.
In C#, the largest part of a TimeSpan is a day, you can't have a TimeSpan of "one month and one day", because adding that to a DateTime would add a different amount of absolute time depending on the DateTime. You can have a TimeSpan of "32 days", and adding that to any DateTime yields a consistent result.
