To hit someone in the eye, you've got to aim at their eye and land a round there. That is, accuracy at hitting a pre-specified target.
To hit armour in the same location twice, you need either two (or more rounds) delivered consistently on whatever happens to be where the first round lands. It's a case where being a Texas Sharpshooter actually works (painting bullseyes around the bullet holes you just shot into a barn).
A compound impactor with a leading and secondary round might work, for example. Difficult to package into a small-arms round, but possible. Keeping everything on the same impact point would be the crucial element.