You can use less copper for the same power with higher voltage as a reduced current is required for the same power. This is also independent of AC/DC.
We have a single 3kVA inverter for the entire boat. From this we can run clothes washer, power tools, kitchen tools, and blow dryer from our batteries. Modern wall warts are incredibly efficient. You are losing, at most, 3-5% efficiency. Plus, it's really hard to find 12V anything thats any good. A 12VDC vacuum cleaner is a joke compared to a proper AC vacuum cleaner.
Trust me whatever efficiency you think you'll be saving is better off buying more solar or bigger battery bank. Keep the distribution simple, 120/220V. Point of use inverters are for charging laptops in the car.