LNG is 85-95% methane, typically, with ethane making up most of the rest. It contains small amounts of propane and butane.
I hadn't known that SpaceX was using a special grade of ~100% liquefied CH4 as nickik says above.
EDIT: shale gas is richer in ethane and higher hydrocarbons than traditional sources of natural gas. Maybe SpaceX is sticking to 100% methane just so they don't have to ponder variability of composition depending on how gas is being extracted.