The 128kbps was of course very easy to pick out.
I'm of the opinion that 320 vs lossless is meaningless enough to not really bother, but I know for some tracks it was trivial for me to tell the different. Mostly it was the very complex/atmospheric tracks, Mind In A Box being a good example, where 320 lost a notable amount of quality. Probably others like Ne Obliviscaris as well.
The biggest problem with Spotify is that not all of their library is available at 320kbps.