"But....we don't get shocked when we stand out in the sun? And yet solar power is a real thing!"
The reason I said "shocked" is not that shocking is the only way that energy can manifest itself. It's because it's the way that significant static electricity manifests, the claimed mechanism being used to obtain power.
You can tell just by standing in the sunlight that it has substantial energy, because you get warm, along with anything else in the sunlight. Therefore it has at least enough energy to do that. Not to mention power the ecosystem.
"I am sure people scoffed back in the 1800's when scientist first worked with solar power."
With all due respect, you do not appear to be in a position to be lecturing people about this sort of thing. You may not understand how energy works, but some people do.