It is? Which ones? Other than Go, I can not think of a single language that has ":=" as an operator. Java does not, JavaScript does not, C/C++ do not, Ruby does not, I don't think PHP does, Erlang/Elixir do not, Rust does not... (I could be wrong on these, but I've personally never seen it in any of these languages and I can't find any mention of it in these languages' docs).
I tried looking around the internet at various popular programming languages and the only ones I could find that use ":=" are: Pascal, Haskell (but it's used for something else than what Python uses it for), Perl (also used for something else), and Scala (but in Scala it isn't officially documented and doesn't have an 'official' use case).
I don't have a strong opinion about ":=" in Python but I do agree that it's unintuitive and thus not very "Pythonic".