Basically, he sold his soul, and I don't blame him for thinking he's not going to get it back.
My understanding is that it's possible to avoid this through TA or RA positions with tuition waivers, at least at reputable programs. So I think the question of debt should be considered somewhat separately (though not entirely separately, as this insidious form of debt doesn't existing the world of stupid mortgages or credit card irresponsibility, where at least you have the topic to collapse in bankruptcy and, 7+ years later, start anew. Forever debt lives in the hellacious realm of student loans, divorces, and Dickens novels).
I mastered out of my PhD program, largely partly because I got a good job outside with money and fun projects, and partly because I was struggling academically. I do occasionally "wish" (eh, not really) that I had a PhD, but that's because I work in a university (although in a technical track). I accept that research positions aren't open to MS holders in Universities (or in some industry positions), but the degree ceiling definitely extends into non-research positions that would be available to MS (or BS or no degree) holders in non-university tracks. This, however, is my own deal. If I don't like it, I need to leave, so I wouldn't expect anyone to give this complaint much force.
STEM Ph.D.s are like jobs. You get paid a stipend (the financial package typically requires you to work as a TA/RA).
A few data points. My Ph.D. program paid me $30k/yr tax free over 4 years. Prestige scholarship holders were able to get even more, maybe $45k-50k. (my numbers are old -- I got my Ph.D. nearly a decade ago)
I've had friends at Princeton who received packages in the range of $28k-$35k/yr from their engineering depts.
Not a huge amount of money, but enough for a single grad student to survive on. I have a friend who did a Ph.D. in Math at Stanford, and he didn't have to pay cent.
Debt is generally not a common issue for STEM Ph.Ds.
Humanities/Social Science Ph.Ds. on the other hand are a completely different ball game. I've heard that many live in relative penury and rarely finish on-time (taking anywhere from 5-7 years). Humanities Ph.Ds. please add data points.
I know Stanford PhDs have even higher stipends to offset the costs of Palo Alto.
If that's the case, and he can literally just light his diploma on fire and walk out into the world without any huge burdens (like debts), then it does seem strange to say it ruined his life.
Perhaps he let someone go who he really adored and is being romantic. Or maybe he thinks he has to keep following this path.. but if he's free to start over, there's no need to worry about the old ruined life anymore.