Where possible, I want to be your beta tester.
So, how can TweetPerView be improved?
What might be worthwhile is the social-media-isize your video feature. An easy-to-use tool for embedding twitter/facebook/linkedin/whatever posting inside the video sounds relatively useful. Maybe have this stuff pop up when the user pauses the video, or when it ends.
Demanding that people do your advertising for you is a death sentence for using social media. You want to enable them to advertise for you, forcing it just fosters ill will.
Blocking the video with the prompt strikes me as hamfisted. Particularly for a technical audience that's aware of how these sharing mechanisms work.
Or what about something less intrusive that shows up next to the video or slides down like a google video ad after I have been watching for a few minutes. At that point I'm already engaged and more likely to say, "Hey, this is really good - let me tweet it." Maybe you get more traction with the tool that way. I'm not really sure.