https://support.steampowered.com/kb_article.php?ref=5421-QTF...
So if I wouldn't have access to that email account, I couldn't login and lose the Steam account, even when knowing the password.
Although, some of the methods from the link would still work, so that's solved, I guess.
(ETA: Note the reason I mention 50+ is that I specifically vary the length randomly; when I don't the cracks drop to hours apart.)
It's one of two sites that I use TFA for that I don't have a backup for, which is mildly annoying. I do have recovery codes, and will all too happily fall back on SMS.
(NOTE: I didn't even know the PC gaming service steam had a mobile app ;))