It's also approximately the time when the building will be coldest. If there were any thermal expansion/contraction issues, they would have been at a maximum near 1am. The thermal expansion and contraction of concrete and reinforcing steel are nearly identical, but the steel has much higher thermal conductivity and cools off far faster; perhaps something snapped under tension between concrete that was still holding heat from the setting sun and steel that had shrunk in the chill of the night.

Incidentally, that chill is also why the 'low battery' alarms on smoke detectors tend to vexingly wake you up in the middle of the night, rather than conveniently running out in the 16 hours a day you're awake, which you might expect to happen twice as often. No, it's not just a bias that causes you to remember waking up to smoke alarm low battery chirps but not hearing them in the daytime, the electrochemical reaction in the batteries happens more readily at higher temperatures. It's a different chemistry, but the same reason a lead acid car battery has a hard time turning a starter in the dead of winter. The sensors in the smoke alarm always draw the same few microamps of current, but when it's coldest in the middle of the night, the battery is less able to meet the demand, and wakes you from your sleep.