I tried my hand at Dreamweaver back in the day (approx. 2005) and didn't like what it generated. I've written a few pages manually (first when learning HTML ca 2004, then for a personal website in 2014) and it felt much nicer.
I have made Windows applications with GUIs as part of my job and for that I've mainly used WPF written as a mix of XAML and C#, written by hand and inspected in the editor. There are graphical tools, but I've mostly found it more efficient to write what you mean directly.
But how are things actually done in the web development business, nowadays?