Now, I can of course convert my foreign currency to ARS via a central bank, or a regular bank transfer. But here's the thing: official central bank rate for 1 USD is around 100 ARS. The unofficial rate (Western Union, Xoom, Crypto P2P) gives me 200 ARS for 1 USD. Quite literally double the money. That's a very big deal.
And yes, you're right that there is no inherent need for the blockchain or crypto at all, but the lack of oversight is probably the only reason why it is so convenient, and the lack of alternatives, because Western Union and Xoom serve the same purpose, but are much slower (days instead of minutes) and are bombarded with government restrictions.
I could, of course, try to find people here directly who want to buy my USD for ARS, and it would function the same way, but Binance P2P offers a marketplace website for that without me needing to find any of the people myself, equipped with escrow functionality so I won't get scammed.