The concentrator mirrors had to be aimed within about 2 degrees to aim the light onto the active area of the cells. I tried using a pair of photodiodes as the sensor, and it worked well in early prototypes. We flew out to Australia before the system was fully integrated into the car, though. In the real setup it just wasn't precise enough. On top of that, the aerodynamically shaped acrylic window surfaces created weird refractions and reflections that made the accuracy poor as well.
I had a couple weeks to figure something out, with a bunch of PIC18F4680 MCUs on hand, and access to parts from Dick Smith's. I ended up buying a small PAL security camera to experiment with. I went to a nearby photo center and got some overexposed film negative to use as an IR-passing filter. With enough layers of film, the camera image was completely black other than a white dot when pointed at the sun. Looking at the analog video signal on a scope, I was able to rig up a couple fine-tuneable voltage dividers and then use the MCU's dual comparator peripheral to generate interrupts on sync pulses and on white pixels. I could then count scan lines, and detect scan lines with the sun in them, giving me a Y coordinate precise to a fraction of a degree. I also got an X coordinate by timing between syncs and white pixels, but I didn't need it for control. I then mounted the camera on the concentrator mechanism, and wrote a basic PID controller.
It worked pretty well, and we were able to happily concentrate sunlight while driving at highway speeds.
It turned out the linear servo mechanism had a design flaw, where it would lose too much mechanical advantage at the extremes, and in the presence of road vibrations it would jam. We discovered this fairly early on in the race. Luckily I had wireless control of the motor over our telemetry system, allowing me to keep the motor from burning out. We drove a couple hours with the system jammed, taking the power hit over losing race time. Someone realized we would be driving over a "cattle grid" soon, and we had the idea to try running the motor at full torque to see if the shock would be enough to unjam the mirrors. It worked, and we suddenly started getting several hundred watts of additional power! After that day, we tied a string to the mechanism and routed it up to the driver cockpit. Whenever the mirrors got stuck after that, we simply radioed the driver and they gave the string a yank.