Ideally reproduce it with mainline kernel or most recent stable. And post the details on the linux-btrfs list. They are responsive to bug reports.
If you depend on LTS kernels then it's, OK to also include in the report the problem happens with X kernel but not Y kernel. Upstream only backports a subset of fixes and features to stable. Maybe the fix was missed and should have gone to stable or maybe it was too hard to backports.
These are general rules for kernel development, it's not btrfs specific. You'll find XFS and i915 devs asking for testing with more recent kernels too.
But in any case, problems won't get fixed without a report on an appropriate list.