Google (or any network) could make it easier for us to use the feature. Facebook has figured this out and actively has some features to help.
The main ones that come to mind are the ability for other people to create relationships, whether personal or work related. This eliminates some of the work when building your profile. Then Facebook implemented the auto-grouping of lists depending on employers, previous interaction, locations, etc. And lastly, they monitor your graph on a daily basis and serve up possible additions to your friend lists which can be added with a simple click.
Google could have done a little of this using Google data such as Gmail lists and all, but they haven't (yet). Personally, I think Facebook's lists and grouping feature is far superior and I'm actually finding out from non-technical friends that they're actually using the friend lists. I suppose this has to do with Facebook automatically pushing a number of default lists to users...