A site can be crawled from any number of Googlebot IP addresses, and so blocking all except one doesn't help in throttling crawling.
If you verify the site in Webmaster Tools, we have a tool you can use to set a slower crawl rate for Googlebot, regardless of which specific IP address ends up crawling the site.
Let me know if you need more help.
Edit Detailed instructions to set a custom crawl rate:
1. Verify the site in Webmaster Tools.
2. On the site's dashboard, the left hand side menu has an entry called Site Settings. Expand that and choose the Settings submenu.
3. The page there has a crawl rate setting (last one). It defaults to " Let Google determine my crawl rate (recommended)". Select "Set custom crawl rate" instead.
4. That opens up a form and choose his desired crawl rate in crawls per second.
If there is a specific problem with Googlebot, you can reach the team as follows:
1. To the right hand side of the Crawl Rate setting is a link called "Learn More". Click that to open a yellow box. 2. In the box is a link called Report a problem with Googlebot which will take you to form you can fill out with full details.
Thanks!
Pierre