Even at my own mediocre level of 1800, I definitely do not score 0.25 against 2000 rated players. More like 0.1 if I'm feeling sharp.
The back of the envelope percentage calculation absolutely does not apply at this level of chess. In reality if Niemann were to play Magnus in 100 games, he would be exceedingly lucky to win one game.
I mean, you can look at the stats. They play all the time and while it becomes less accurate at the highest ratings (more so at the 2800+ level), 2400 vs 2600 does still result in something in the general range of 0.25. However, if it's 0.1 (like in your example) then my point is even stronger since it would be even harder to turn that into a win consistently with just 1 hint.
>Even at my own mediocre level of 1800, I definitely do not score 0.25 against 2000 rated players.
If you are noticing that at your level, it is probably either selective memory or specific to your play as ELO-estimated winning chances hold up well enough at 1800-2000.
(FWIW, I am 2000 USCF and an expected value of 0.24 vs a 2200 and 0.76 vs an 1800 feels quite reasonable to me.)