I mean, just talk to your kids about sex. You're not going to succeed in censoring their internet activity. Any more than you'll succeed in stopping them from sneaking out and going to parties or drinking with their friends - did your parents try to stop you from sneaking out? Did it work? Because I got really good at scaling fences and climbing out of windows.
But in the effort you will send the message that there is no trust between you and your child, and they won't feel safe talking to you should they need to. If you take the attitude that sex is something illicit, they will take the message that it's something to keep secret from you.