At least in the US (not sure where you are), combustion boiler/furnace efficiency is required to be calculated using the HHV, which includes the heat of vaporization, not the LHV. The result is that even the highest efficiency condensing combustion heating systems all have rated efficiencies below 100%, which makes sense thermodynamically.
It seems that the standard in Europe is to instead calculate efficiency using LHV, resulting in the efficiency rating over 100% for condensing boiler. > 100% doesn't make sense thermodynamically, but is good enough for comparing when the same calculation is used.
Either way, it should be made more clear in the UI that it is using LHV.