Perhaps, but even with an arbitrarily good training set, the LLM would still be constrained by it's own architectural limits. e.g. If a problem can't be broken down into sub-problems that each require <= N sequential steps, then an N-layer transformer will never be able to solve it.
Even if the architectural shortcomings were all fixed, it seems "[pre-training] data is all you need" would still be false, because there is no getting around the need for personal experience, for the same reasons that is true for us...
Perhaps most fundamentally, any action/prediction you make can only based on the content of your own mind, not the mind of a tutor you are trying to copy. Even if the tutor diligently tries to communicate all nuances and contingencies of a skill to you, those are still all relative to his/her own internal world model, not the one in your head. You will need to practice and correct to adapt the instructions to yourself.