What is the difference if you answer in 10 minutes, 6 hours or 24 hours? Are you competing on time of response so if you're fast you're getting the deal?
I don’t read or action all emails instantly, but I am very aware of the ones I need to, or when I am in a period of high focus that needs information fast.
In an ideal world I’d be in an office with all the people I needed around me, all with the same focus and priorities, but that is rarely the case. So to excel at my job I need to make connections fast and respond fast. (Note this isn’t just email, this is just for my communications in general.)
Doing it during business hours matters more than off hours outside of major deadlines or event prep.
With many organizations, if you want to give this impression and also shut down communications to focus, you need blocks of time outside of business hours where you focus. For example, I know a responsive executive who cannot be reached from 6am-9am every weekday, when most people aren't trying to get hold of him. This is when he writes and reads. Even then, his assistant fields communications so he doesn't seem to have disappeared.
Not saying you should do this or that it's for everybody.
Exec asked for some business information information while traveling.
I replied promptly, sending a link to a webpage, within the proper process for secure data sharing according to company policy. This required exec to visit our internal website to view the information.
A teammate emailed the information directly, violating policy and good data stewardship.
CEO replied to teammate's email with a big group thank you for "emailing the information quickly".