Why mandate the use of Neighbor Discovery Protocol instead of the much simpler ARP?
Why change the rules for UDP checksums? The checksum field in UDP over IPv4 is optional. The checksum field in UDP over IPv6 is required. This is a major pain for protocols that change fields in transit, such as PTP.
I could go on. There are important reasons for each of these decisions, but the fact is that every little change slows adoption. IETF could have stayed focused on solving address scarcity alone, but instead they chose to boil the ocean.