I feel as though not enough attention is given to how std is designed. For example: [u8], str, Path, and OsStr may be confusing at first, but when you understand why they are there any other approach feels icky. std guides you down a path of caring about things that really should matter (at least if you're only unwrapping provably safe values).
Have you considered what happens if not-utf8 data winds up in an environment variable that you are writing to stdout? What if it contains malicious VT commands?