The usual outcome of this assumption is that a user complains to the compiler that it doesn't produce the expected assembly code, which the compiler ignores because they never guaranteed any particular assembly output.
This is especially true for the kinds of implicit assembly guarantees people want when working with exotic hardware. Compilers will happily merge loads and stores into larger load/stores, for example, so if you need to issue two adjacent byte loads as two byte loads and not one 16-bit load, then you should use inline assembly and not C code.