Not necessarily. If you are computing an aggregation for instance, if your computation is recursive and not tail call optimized, it may overflow the stack but the fixed version will not use additional memory for each iteration.
Otherwise, indeed stack is memory, but the memory in general is usually way less limited than the stack and also running out of memory doesn't have the same security implications as overflowing an unprotected stack.
And, unless you manage to encode everything in the stack, your iterative version will probably take the same amount of memory as your non-optimized recursive version, minus the space used for the stack.