A good place for juniors to start would be in normal web shops, not high-pressure startups.
Do you think Tesla Motors grabbed a few engineering grads and shop floor assistants, chucked them in a room and hoped they'd "grow into" knowing how to make an electric car? Of course not - for a startup like that, timely and accurate execution is absolutely critical and they would have hired the best, most experienced people they could get. I don't see why software startups are any different.