Nix(OS) is aware of namespaces, and can use them (in fact, the aforementioned gaming support relies on them), but versioning packages still works better than versioning the system in most cases.
Consider three packages, A, B, and C. B has two versions, A and C have one.
- A-1.0.0 depends on B-2.0.0 and C-1.0.0.
- C-1.0.0 depends on B-1.0.0.
If A gets a path to a file in B-2.0.0 and wants to share it with C (for example, C might provide binaries it can run on files, or C might be a daemon), it needs C to be in a mount namespace with B-2.0.0. However, without Nix-store-like directory structure, mounting B-2.0.0's files will overwrite B-1.0.0's, so C may fail to start or misbehave.