The grid uses AC (not DC), running at 50 Hz (cycles per second). So the voltage is going up and down at that frequency, in a sine-wave pattern.
If you try to connect another generator to the grid, it needs to be at the same point (phase) in the sine-wave cycle, so that its power contribution is added, not subtracted.
If it's not in sync, huge currents can flow, causing damage. Sort of like connecting jumper cables backwards.