2022-ish: Titan created (based on existed of https://web.archive.org/web/20220126075826/https://transjovi...).
The spec for Titan (https://portal.mozz.us/gemini/transjovian.org/titan/page/The...?) appears to be an implementation of PUT for Gemini, but since Gemini doesn't have verbs (GET is implied) it does it by creating a whole new "protocol" titan://
So you're right, they didn't extend the Gemini protocol, they created an entirely new protocol which many clients, servers, and libraries now implement because the functionality was desirable.
Wonder what they'll call the protocol that implements DELETE... maybe Deorbit?
Edit: oh there's also Spartan (2022), another protocol which is Gemini but if there are bytes after the request line, it's an implicit PUT: https://raw.githubusercontent.com/michael-lazar/spartan/refs...