Yes, the earliest mainboards I know of with on-board I/O including ATA is around Socket 5, the first mainstream Pentium boards. Some slightly older Socket 4 boards (circa 1994) have on-board I/O, but they weren't as common.
My 486 and earlier systems have all I/O provided by ISA cards, other than the 5-pin DIN keyboard port which was standard since the original PC.