They could try, but not even China could build an impregnable firewall.
"Sorry, you can't use this evidence that exonerates you - it would be bad for the government."
They can learn from Russia. Censorship in Russia now surpassed China. TSPU are now in every ISP facility. They pass all traffic through them and allow arbitrary bans of specific resources/protocols/etc in specific cities or whole regions.
It's the same mechanism that makes us consider the 1% of flat earthers crazy. Sadly the mechanism works based on how many people believe a thing, not whether it's true, so it can also block true things if only 1% of people believe them.
We don't think they are crazy because they are not 1%, they are majority.
Most people think flat earthers are crazy not because they proved them wrong. Just most people around them think flat earthers are crazy and that's enough.