a "podcast" is just an mp3 file, usually fetched by finding the URL via an rss feed. I am asking, perhaps a bit cheekily, "who is putting ads in", because that isn't a "feature" of podcasts. Stop getting podcasts from places that put ads in, support "podcasters" that don't do this scummy crap.
It's just an mp3 file!
edit: I should point out that i pitched, to Apple, the ability to dynamically insert ads sometime around ipod 5th gen, 2005-2006, but not for podcasts, but for downloadable videos, like "last night's TV show". I'm sorry i did this. I don't mean i had the idea and said "hey this is an idea", i had the entire infrastructure documented, it was drop in and go. Whoops.