(This has bitten me before. I don't know why it was done that way.)
It even had the original XUL-based DownThemAll version, got disabled after XUL addons were disabled and some time one or two years later it got re-enabled again after the dev released a webextensions compatible version (sadly with several limitations, but still useful for bulk downloads).
Amusingly, there are a couple Windows absolute paths in there even though this profile has been on Linux for a few years now :-P
> there is no migration path supported at this point: only new profiles are expected to use the new setup. Migrating manually is at your own risk, make a backup before.
I'll try to do it manually, replacing paths in the couple of files mentioned above first.