You can use everything as a radiator, but you can't use everything as a radiator sufficiently efficient to cool hot chips to safe operating temperature, particularly not if that thing is a thin panel intentionally oriented to capture the sun's rays to convert them to energy. Sure, you can absolutely build a radiator in the shade of the panels (it's the most logical place), but it's going to involve extra mass.

You can rivet people onto the outside of the ISS to radiate heat, too, but it may be detrimental to the overall system.