Sure, the syntax is unique, but it's fairly easy to get over that. I guess I'm comparing to Rust, where not only is syntax different, but data structures like a tree with parent references aren't as straightforward (nor idiomatic), and there's a lot more explicit methods that requires knowing which are important and which are just noise (e.g. unwrap, as_ref).
I would argue that after a short tutorial on basic syntax, it's easier for a Python/JavaScript programmer to understand Go code than Rust.