His alignment with Russia consists of being there trying to catch another flight while his passport was revoked by the US administration.
And the appeals for asylum to non-dictatorships (such as most EU countries) fell on deaf ears - nevermind that asylum in "allied" countries probably isn't safe in the first place.
Look at Germany: Every spot within ~150 miles from a US controlled military base or embassy, and known to be used as hub for that extra-legal rendition program (where the German government looked the other way even when the US went after a German citizen).
After the US and UK, such countries are certainly the last place I'd try to hide from the US administration if I had to suspect that they're really eager to get me.
He should also plan his route so that he doesn't cross US-allied airspace - see the grounding of the Bolivian president's plane in Europe over suspicions that Snowden might be a passenger.
With all that, we're not talking about alignment but about a lack of options.