I witnessed a test of a small (500 lb thrust) H2/F2 rocket engine. The fuel & oxidizer were fed into the combustion chamber with small turbo pumps, which was the point of the test. The native fluoride protective coating failed in the F2 turbo pump, and there was an explosion with subsequent metal/fluorine fire.
Blockhouse sealed off and we all grabbed the Scott packs as a yellowish cloud of fluorine drifted by, setting fire to sagebrush as it went. Can't beat exotic propellants for excitement.