I don't accept that 'effectively impossible' means 'can happen, but probably doesn't happen very often'.
Rust has many other unsafe code paths than ffi; low level optimisations, dynamic libraries, etc.
Unless you go out of your way or are doing low level work, your code will not contain such bugs, and if you used no dependencies that do anything meaningful, what you said is plausibly true.
...but what are we trying to argue here?
That you can build a contrived rust program that doesn't crash?
Or that if you build an arbitrary program in rust, using arbitrary dependencies to do meaningful work (that will invoke a c library at some point, and talk to device drivers), that it wont crash?
In my view 'effectively impossible' is faaaaaar over stepping the bounds of reality.