Good question. I went to the Bifront/Asgard setup directly without prior Schiit experience (though I did have Sennheiser experience). My previous setup was constructed for a different environment, e.g, speakers and a Denon with a built in DAC/amp.
I can absolutely tell the details in certain albums using the new setup. Hearing the difference between FLAC/ALE and something encoded at 320bps or higher is really dependent on the material though.