Semantic analysis of the Federalist Papers[0] comes to mind. It originally was not known which individual author wrote which paper, but stylometric analysis (i.e. word-counting and matching word frequency distributions of the unlabelled papers against those of labelled papers (in which the author was known)) made it reasonably straight-forward to identify the original authors.
[0] A set of historical papers of great political importance. http://en.wikipedia.org/wiki/The_Federalist_Papers