The basis of human irrationality is not tied to the basis of LLM irrationality.
LLMs don't get to make value judgements, because they don't "understand". They predict the subsequent points of a pattern given a starting point.
Humans do that, but they also jade their perception with emotive ethics, desires, optimism and pessimism.
It is impossible to say that two humans with the exact same experience would always come to the same conclusion, because two humans will never have the exact same experience. Inputs include emotional state triggered by hormones, physical or mental stress, and so forth, which are often not immediately relevant to any particular decision, but carried over from prior states and biological processes.