The truly break-out companies founded in markets where customers are willing to pay, are started by entrepreneurs over 28. Age is not a hard rule but we talking about averages here. Steve blanks spoke well about how he started up his companies while still managing family life. Check quora for famous tech founders over 30 and their take on it.
An example about how a person over 30 starts a business from Quora:
Marc Bodnick, Co-Founder, Elevation Partners
We did it by starting with a profitable service line.
I was 34 when I founded Arcstone. We had three young kids (we now have four). I was coming off a VC salary of ~$250K, and yet didn't have much savings to speak of. I started Arcstone with $18K borrowed from my brother-in-law, and a couple credit cards to service revolving debt.
We started a service business targeting a specific, relevant pain point, which has a quick sales cycle. We became profitable immediately; with our profits we both fed ourselves and invested in technology and infrastructure. We were careful not to overbuild on our way up, though some expenditures (like our 5-year lease) were taken with a leap of faith.
Three+ years on, we are a nationally respected financial services firm (primarily in the valuation niche) with a healthy top (and bottom) line, and a very happy and dedicated team of seven.
Getting out of the Silicon Valley mindset -- Seed/A/B/C/Exit -- has been incredibly liberating.